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Regio- and Stereoselective Enolizations Using Calcium Bis(hexamethyldisilazide) as a Base: Synthetic, Solid-State, and Solution Studies
Unsaturation in Binuclear Cyclobutadiene Iron Carbonyls: Triplet Structures, Four-Electron Bridging Carbonyl Groups, and Perpendicular Structures
Reaction of 6-Methyl-2,2′-bipyridine with 1,2-Os3(CO)10(MeCN)2: Syntheses, Reductive Elimination/Ligand Displacement Kinetics, and X-ray Diffraction Structures of the Isomeric Clusters HOs3(CO)9(μ2-N2C11H9) and H2Os3(CO)8(μ3-N2C11H8)
[H(EtOH)2][{OsCl(η4-COD)}2(μ-H)(μ-Cl)2] as an Intermediate for the Preparation of [OsCl2(COD)]x and Its Activity as an Ionic Hydrogenation and Etherification Catalyst
New Palladacycles Containing Terdentate [C,N,O]n− (n = 0, 1, 2) or Tetradentate [N,C,O,N′]n− (n = 1, 2) Ligands. The First 1,2-Dihydroquinazoline-4-yl Complexes
Insight into the Mechanism of Platinum-Catalyzed Cross-Coupling of Polyfluoroaryl Imines
Aromatic C−H Activation and Catalytic Hydrophenylation of Ethylene by TpRu{P(OCH2)3CEt}(NCMe)Ph
Mono(cyclopentadienyl)titanium(II) Complexes with Hydride, Alkyl, and Tetrahydroborate Ligands: Synthesis, Crystal Structures, and Ethylene Dimerization and Trimerization Catalysis
Phosphorus and Olefin Substituent Effects on the Insertion Chemistry of Nickel(II) Hydride Complexes Containing Amido Diphosphine Ligands
Rhenium(I) Tricarbonyl Complexes with New Pyridine Ligands Containing Crown Ether-Annelated or Anthracene-Functionalized 1,3-Dithiole-2-ylidene
R3C−H→SiFR3 Agostic Interaction
A Ruthenium-Based Catalyst System for Hydrovinylation at Room Temperature
Introduction to the Review by Cabeza and García-Álvarez in This Issue of Organometallics
Selective Assembly of Trinuclear Rare-Earth Alkyl Hydrido Clusters Supported by Amidopyridinate Ligands
The New Tridentate Ligand CpSiNSiCp and Its Zirconium Complexes: Incorporation of Two Bridged Constrained-Geometry Units into One Molecule
Electronic Structure of Stable Radicals of the Heavy Group 14 Elements: UV-Photoelectron Spectroscopy Characterization
A Chiral Phosphoramidite beyond Monodentate Coordination: Secondary π-Interactions Turn a Dangling Aryl into a Two-, Four-, or Six-Electron Donor in d6 and d8 Complexes
Copper(I) Diphosphine Catalysts for C−N Bond Formation: Synthesis, Structure, and Ligand Effects
Catalytic Annulation of Heterocycles via a Novel Redox Process Involving the Imidazolium Salt N-Heterocyclic Carbene Couple
Novel Expanded Ring N-Heterocyclic Carbenes: Free Carbenes, Silver Complexes, And Structures
Amine-Assisted C−Cl Bond Activation of Aryl Chlorides by a (Phebox)Rh-Chloro Complex
Synthesis of Rhenium Carbonyl Complexes Bearing Substituted Pyrrolyl Ligands
Chromium Complexes with Me2Si-Bridged Cyclopentadienyl-imidazolin-2-imine Ligands: Synthesis, Structure, and Use in Ethylene Polymerization Catalysis
Coupling an Electrospray Ionization Mass Spectrometer with a Glovebox: A Straightforward, Powerful, and Convenient Combination for Analysis of Air-Sensitive Organometallics
Structural Features of Lithio[3]ferrocenophane Systems Bearing Stabilizing Dimethylamino Substituents
Unusual Selectivity-Determining Factors in the Phosphine-Free Heck Arylation of Allyl Ethers
Mixed-Valence Manganese Carbonyl Complexes with Supersilyl Thiolate Ligands: [(OC)4Mn(μ-SSitBu3)2Mn(THF)X] (X = Br, SSitBu3) and Na(THF)6[(OC)3Mn(μ-SSitBu3)3MnSSitBu3]
Synthesis, Characterization, and Properties of Luminescent Organoiridium(III) Polypyridine Complexes Appended with an Alkyl Chain and Their Interactions with Lipid Bilayers, Surfactants, and Living Cells
Novel μ-CO-Containing Butterfly Fe/S Cluster Anions Generated from Tetrathiols, Fe3(CO)12, and Et3N: Their Reactions with Electrophiles To Give Neutral Butterfly Fe/S Cluster Complexes
Novel 9-Nickelafluorenyl Sandwich Complexes of Nickel(II) and Cobalt(II)
Regioselective Ortho Palladation of Stabilized Iminophosphoranes in Exo Positions: Scope, Limitations, and Mechanistic Insights
The Chloromethylgermyl Complexes (η5-C5H5)M(CO)nGeR2CH2Cl [M = Fe (n = 2), Mo, W (n = 3)]: Rearrangements, Transformations to 1-Germa-3-metallacyclobutanes (η5-C5H4)M(CO)nCH2GeR2, and their Ring-Opening Polymerizations
Synthesis, Structures, and Coordinating Properties of Phosphole-Containing Hybrid Calixpyrroles
General Routes to Alkyl Phosphatrioxaadamantane Ligands
Silicon−Carbon Unsaturated Compounds. 75. Thermal Isomerization of 2-Alkyl- and 2-Aryl-2-trimethylsiloxy-1,1-bis(trimethylsilyl)-1-silacyclohex-4-enes
A Bis(1,2-Azaborolyl)yttrium Alkyl Complex: Synthesis, Structure, and Polymerization Study
Orthoplatination of Primary Amines
1,2-Dibromo- and 1,2-Diiodotetrafluorobenzene as Precursors of Anionic Homo- and Heterometallic Gold Complexes
From Functional Phospholide Ions to Bifunctional 1,1′-Diphosphaferrocenes
Weak η2-Olefin Bonding in Palladium and Platinum Allyl Cationic Complexes Containing Chiral Monodentate Ligands with α-Phenyl Methyl Amine Side Chains
Dihydrogen Loss from a 14-Electron Rhodium(III) Bis-Phosphine Dihydride To Give a Rhodium(I) Complex That Undergoes Oxidative Addition with Aryl Chlorides
Preparation and Reactions of Base-Free Bis(1,3-di-tert-butylcyclopentadienyl)titanium, Cp′2Ti, and Related Compounds
Highly Efficient Hydrosilylation of Alkenes by Organoyttrium Catalysts with Sterically Demanding Amidinate and Guanidinate Ligands
Examination of the Pyridine Binding to the Bifunctional Lewis Acid B,B′-Diphenyldiboradiferrocene
Base-Promoted Selective Activation of Benzylic Carbon−Hydrogen Bonds of Toluenes by Iridium(III) Porphyrin
Investigation into the Phosphorescence of a Series of Regioisomeric Iridium(III) Complexes
Synthesis and Protonation Studies of Cp*Os(dppe)H: Kinetic versus Thermodynamic Control
Synthesis and Characterization of Chalcogenolato-Bridged Allyl Palladium Complexes: Versatile Precursors for Palladium Chalcogenides
Direct Formation of Propargyltin Compounds via C−H Activation
Preparation, X-ray Structure, and Reactivity of an Osmium-Hydroxo Complex Stabilized by an N-Heterocyclic Carbene Ligand: A Base-Free Catalytic Precursor for Hydrogen Transfer from 2-Propanol to Aldehydes
Exceptionally Efficient Unsymmetrical Ruthenium(II) NNN Complex Catalysts Bearing a Pyridyl-Based Pyrazolyl−Imidazolyl Ligand for Transfer Hydrogenation of Ketones
Basal-Edge-Bridged Square-Pyramidal Hexaruthenium Carbonyl Clusters: Synthesis, Structure, and Reactivity
Coordination and Activation of Diazoalkanes in the Presence of Rh/Ru and Rh/Os Metal Combinations
Coupling of Terminal Alkynes and Isonitriles by Organoactinide Complexes: Scope and Mechanistic Insights
Rhodium(III) Complexes Containing C4-Bound N-Heterocyclic Carbenes: Synthesis, Coordination Chemistry, and Catalytic Activity in Transfer Hydrogenation
Synthetic, Structural, and Thermochemical Studies of N-Heterocyclic Carbene (NHC) and Tertiary Phosphine Ligands in the [(L)2Ni(CO)2] (L = PR3, NHC) System
Synthesis and Reactivity of (η1-Alkynyl)diorganoplatinum(IV) Species, Including Structural Studies of PtIMe(p-Tol)(CCSiMe3)(dmpe) [dmpe = 1,2-bis(dimethylphosphino)ethane] and the Platinum(II) Reagent PtPh2(dmpe)
Isolation, X-ray Crystal Structure, and Reactivity of a New C−H Carbene Complex of (5,10,15,20-Tetraphenylporphyrinato)ruthenium(II)
Phospha-Scorpionate Complexes by Click Chemistry using Phenyl Azide and Ethynylphosphine Oxides
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