| Attributs | Valeurs |
|---|
| type
| |
| Is Part Of
| |
| Subject
| |
| Title
| - Isolation, X-ray Crystal Structure, and Reactivity of a New C−H Carbene Complex of (5,10,15,20-Tetraphenylporphyrinato)ruthenium(II)
|
| has manifestation of work
| |
| related by
| |
| Author
| |
| Abstract
| - The new (porphyrin)ruthenium(II) carbene complex 1 has been prepared by treating (TPP)Ru(CO)(EtOH) with excess 2,6-di-tert-butyl-4-methylphenyl diazoacetate and characterized by X-ray crystal structure analysis due to a kinetic stability. The reactivity of 1 toward axial ligands (CO, pyridine, dimethylphenylphosphine) and the asymmetric cyclopropanation of styrene with this bulky diazoacetate ester catalyzed by ruthenium Halterman porphyrin are also presented.
|
| Alternative Title
| - C−H Carbene Complex of (5,10,15,20-tetraphenylporphyrinato)ruthenium(II)
|
| is part of this journal
| |
